So I am computing the character table for $S_5$, and the only thing I have yet to understand is how we know the character values for the row relating to the 6-dimensional irrep. The irreps I have are: trivial, sgn, standard, and the product of the standard and sgn. I then computed the dimensions of the remaining irreps using elementary number theory. If I can compute the row for the 6-dimensional irrep, then the rest is not hard by column orthogonality.
The sources I found just sort of state the values or say it is the "exterior square of the standard representation," which we have not discussed in class, so I am not sure if I can use that (not to mention I do not understand it). Is there another way to view this irrep?
It may be easier to view the 6-d rep as a component of the exterior square of the natural (non-irreducible) 5-dimensional representation $V$. At least I think it is easier to figure out the character of $\wedge^2V$. Bear with me for a moment.
Let $x_1,x_2,x_3,x_4,x_5$ be a basis of $V$ with $S_5$ acting by permuting the indices, $\sigma(x_i)=x_{\sigma(i)}$. A basis of $\wedge^2V$ then consists of the wedge products $e_{i,j}:=x_i\wedge x_j, 1\le i<j\le 5$. We follow the usual rules: $x_i\wedge x_j=-x_j\wedge x_i$ and $x_i\wedge x_i=0$, so the ten vectors $e_{ij},1\le i<j\le5$ form a basis of $\wedge^2V$.
The group $S_5$ still acts by permuting the indices, $\sigma(e_{i,j})=e_{\sigma(i),\sigma(j)}$. Let's denote the character of $\wedge^2V$ by $\psi$. I will round up the diagonal entries of the matrices of permutations from all the conjugacy classes of $S_5$. All w.r.t. the above basis. Basically we need to keep an eye on pairs of indices such that $\sigma(\{i,j\})=\{i,j\}$, in some order:
Let $\chi_1$ be the 4-dimensional irreducible component of $V$. Given all this (and the census on the sizes of conjugacy classes) it is easy to calculate that $$ \langle\psi,\chi_1\rangle=1\qquad\text{and}\qquad\langle\psi,\psi\rangle=2. $$ This implies that $\psi=\chi_1+\chi_2$ for some previously unknown irreducible character $\chi_2$. The values of $\chi_2$ are easily calculated from the known values of $\psi$ and $\chi_1$.
You can also view $\wedge^2V$ as the antisymmetric part of the tensor product $V\otimes V$. That is the eigenspace corresponding to the eigenvalue $-1$ of the involution $S:V\otimes V\to V\otimes V$ defined on elementary tensors as $S(x\otimes y)=y\otimes x$.