Forgive me in advance if this question seems ridiculous.
Let $X$ be a set. Then "$X\neq\bigcup_{x\in X}\{x\}$ is false" is a true statement.
This statement says that a set is always equal to the union of its elements(points).
Is this axiomatic or can this actually be proven by by something even more obvious than the statement?
When you say "provable" you need to specify some axioms from which this to be proved.
If we consider the axioms of $\sf ZFC$, which are considered more or less the canonical set theory nowadays, then the answer is that yes. We can prove that.
First of all we need to show that if $X$ is a set then $\{\{x\}\mid x\in X\}$ is a set. This is true because $S=\{x\}\mid x\in X\}$ is a definable subset of $\mathcal P(X)$, and the latter exists from the axiom of power set. So using the separation axiom schema we conclude that $\{\{x\}\mid x\in X\}$ is a set.
Now the union $\bigcup_{x\in X}\{x\}$ is the union of $S$. This union exists as a consequence of the axiom of union, which states that if $A$ is a set, then $\{b\mid\exists a\in A:b\in a\}$ is also a set. Call this union of singletons $Y$.
Finally, $X=Y$ due to the axiom of extensionality. Given $x\in X$, $\{x\}$ was an element of $S$, therefore $x\in Y$, and on the other hand if $x\in Y$, then there is some $s\in S$ such that $x\in s$, but if $s\in S$ then $s=\{x'\}$ for some $x'\in X$. So if $x\in s$ it follows that $x=x'$ and therefore $x\in X$. $\square$