I'm looking for a book for someone who only knows high-school level math that will show him what math really is and how amazing it is.
Do you know a book that could do that?
A book to inspire people about math
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The books by William Dunham are very readable (but require a fair bit of work by the reader, and some background). "Euler: Master of us all", "The calculus gallery", and perhaps best for the current question "The mathematical universe" and "Journey through genius" are the ones I've read, and can personally recommend.
Very nice is Nahin's "An imaginary tale: The story of $\sqrt{-1}$".
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Most of those books are either too academic or just not catchy. Here are my suggestions that would go for both experienced mathematicians and newbies:
1) Cedric Villani: Theoreme vivant (http://www.amazon.com/Theoreme-Vivant-French-Cedric-Villani/dp/2253174904/ref=sr_1_2?s=books&ie=UTF8&qid=1395341883&sr=1-2). Also available in german. Not sure if already in english. Includes detailed parts of Villani's research (in LaTex...). But reading the story of how to approach and finally win the prestigious Fields Medal in Mathematics and looking into the head of such a brilliant mind is fascinating for non-mathematicians.
2) Logicomix: An epic search for truth (http://www.amazon.de/Logicomix-An-Epic-Search-Truth/dp/0747597200). A brilliant graphic novel about the life of Bertrand Russell, touching deep insights into real mathematics and being catchy at the same time.
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Evan a person with a short attention span ought to be able to make it through Mathematics: A Very Short Introduction by Timothy Gowers. The author is a Fields medalist.
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I don't know of a book, but I know of a simple problem in applied math that could interest your friend. He could study a very simple physical system in some configuration space, and use basic mathematics to compute all the possible directions that this system can move towards in the larger space (there will inevitably be constraints, which you can further study). This can be done with the computation of "Lie Brackets" but don't be afraid of this fancy term; it is mostly just calculus and basic trigonometry and geometry from high school.
The simplest, classic first example would be the random car-parking example. Feel free to look it up.
Charles W. Trigg, Mathematical Quickies: $270$ Stimulating Problems with Solutions.