Determine the truth or falsity of the following proposition.
If $A$ is a square matrix of order $n$ and is invertible, then $A$ is diagonalizable.
This proposition is false. For example, the matrix
$$A = \begin{pmatrix} 1 &0 \\ 1 & 1\end{pmatrix}$$
is invertible, but not diagonalizable. Since it has only a single eigenspace $E_{\lambda =1}=\textrm{span}\left \{ \left ( 0,1 \right ) \right \}$.
How to demonstrate that falsehood in general?
I don't think there is a way to demonstrate this in general. Such statements are considered false, so long as you can provide a case that the given condition is wrong.
The above statement is false, because there are square matrices that don't match that condition such as:
$\left ( \begin{matrix} 1 & 0 \\ 1 & 1 \end{matrix} \right )$, $\left ( \begin{matrix} 1 & 1 \\ 0 & 1 \end{matrix} \right )$ etc...