Does $$o(\frac{1}{n^{2}})+\cdots+o(\frac{n}{n^{2}})=o(1)$$hold?
I know that when there is only finite terms the addition is valid. But in this situation, I don't know whether I can use the addition of limit. Hope for your hint.
On
No it does't hold in general since
$$f(n)=o\left(\frac{1}{n^{2}}\right)+\cdots+o\left(\frac{n}{n^{2}}\right)\iff f(n)=\omega_1 \left(\frac{1}{n}\right) \frac{1}{n^{2}} + \cdots +\omega_n \left(\frac{1}{n}\right) \frac{1}{n}$$
and we don't have information about $\omega_i \left(\frac{i}{n}\right)\to 0$.
To address the OP's original problem, if $f$ is differentiable at $0$, there is some $\epsilon:x\mapsto \epsilon(x)$ such that $f(x) = f(0)+xf'(0)+x\epsilon(x)$, $\epsilon(0)=0$ and $\epsilon$ is continuous at $0$.
Assuming $f(0)=0$, $\sum_{k=1}^n f(\frac{k}{n^2})=f'(0)\frac 1n\sum_{k=1}^n \frac{k}{n} + \sum_{k=1}^n \frac{k}{n^2}\epsilon(\frac{k}{n^2})$
Consider $\gamma >0$. There exists some $\delta >0$ such that $|x|\leq \delta \implies |\epsilon(x)|\leq \gamma $. For $n$ larger than $\frac{1}{\delta} +1$, $$\left| \sum_{k=1}^n \frac{k}{n^2}\epsilon(\frac{k}{n^2}) \right|\leq \gamma \frac 1n n = \gamma$$
Thus $\lim_n \sum_{k=1}^n \frac{k}{n^2}\epsilon(\frac{k}{n^2}) = 0$
Since $\frac 1n\sum_{k=1}^n \frac{k}{n}$ is a Riemann sum that converges to $\frac 12$, $\sum_{k=1}^n f(\frac{k}{n^2})$ converges to $\frac{f'(0)}{2}$.