A relation $R$ is defined on $\mathbb{Z}$ by $aRb$ if and only if $2a + 2b\equiv 0\pmod 4$. Prove that $R$ is an equivalence relation.
My method:
Let $a \in \mathbb{Z}$ be given. So, for any $a \in \mathbb{Z}$, we have $2a +2a = 4a$. Since $4a$ is divisible by $4$, it is congruent to $0\pmod 4$. It follows that $aRa$. So, $R$ is reflexive. Then, for any $a, b \in \mathbb{Z}$, we have $2a + 2b = 2b + 2a$. It follows that if $aRb$ then $bRa$, then $R$ is symmetric. Finally, we assume that $aRb$ and $bRc$, so we have $(2a + 2b) + (2b + 2c) = (2a + 2c) + 4b\equiv 2a + 2c\pmod 4$, since $4b\equiv 0\pmod 4$. Then if $2a + 2c\equiv 0\pmod 4$ and $2b + 2c\equiv 0\pmod 4$, it follows that $2a + 2c\equiv 0\pmod 4$. Then $R$ is transitive.
I think this needs some work, but I am not sure what else needs to be done. Would I need a different way to find if it's reflexive, symmetric, or transitive?
Your method is fine.
You can shorten it by noticing that $$ 2a+2b=4k, $$ for some integer $k$, if and only if $a+b=2k$. This should put you on the track that your relation $R$ is just congruence modulo $2$, so $a\mathrel{R}b$ if and only if $a$ and $b$ are both even or both odd.