Then $$\int_{-\infty}^{\infty}x^{2}\frac{1}{\sigma\sqrt{2\pi}}\exp(-\frac{x^{2}}{2\sigma^{2}})\,dx=\frac{1}{\sqrt{2\pi}\sigma}\frac{1}{2}\frac{\sqrt{\pi}}{\sqrt{\frac{1}{2^{3}\sigma^{6}}}}=\sigma^{2}$$(By using the "convenient trick").
Now if $X\sim N(\mu,\sigma^{2})$ then $X-\mu\sim N(0,\sigma^{2})$.
So $Var(X-\mu)=\sigma^{2}$.
So $$E((X-\mu)^{2})=\sigma^{2} $$.
$\implies E(X^{2}+\mu^{2}-2X\mu)=\sigma^{2}$
$\implies E(X^{2})+\mu^{2}-2\mu E(X)=\sigma^{2}$
So $E(X^{2})-\mu^{2}=\sigma^{2}\implies E(X^{2})-(E(X))^{2}=Var(X)=\sigma^{2}$ .
There are other ways to calculate the integral $\int_{-\infty}^{\infty}x^{2}e^{-x^{2}}\,dx$.
We have:- $$\frac{1}{\sqrt{2\pi}\sigma}\int_{-\infty}^{\infty}(x-\mu)^{2}\exp(-\frac{(x-\mu)^{2}}{2\sigma^{2}})\,dx$$
We are then substituting $\frac{x-\mu}{\sqrt{2}\sigma}=y$
So $dy=\frac{dx}{\sqrt{2}\sigma}$
Using this we get:-
$$\frac{1}{\sqrt{\pi}}\int_{-\infty}^{\infty}2\sigma^{2}y^{2}\exp(-y^{2})\,dy$$
Now use the "convenient trick" to get :-
$$\frac{2\sigma^{2}}{\sqrt{\pi}}\cdot\frac{1}{2}\cdot\sqrt{\pi}=\sigma^{2}$$
Hence you have the result.
You can also proceed like this:-
Assume $\mu=0$.
Then $$\int_{-\infty}^{\infty}x^{2}\frac{1}{\sigma\sqrt{2\pi}}\exp(-\frac{x^{2}}{2\sigma^{2}})\,dx=\frac{1}{\sqrt{2\pi}\sigma}\frac{1}{2}\frac{\sqrt{\pi}}{\sqrt{\frac{1}{2^{3}\sigma^{6}}}}=\sigma^{2}$$(By using the "convenient trick").
Now if $X\sim N(\mu,\sigma^{2})$ then $X-\mu\sim N(0,\sigma^{2})$.
So $Var(X-\mu)=\sigma^{2}$.
So $$E((X-\mu)^{2})=\sigma^{2} $$.
$\implies E(X^{2}+\mu^{2}-2X\mu)=\sigma^{2}$
$\implies E(X^{2})+\mu^{2}-2\mu E(X)=\sigma^{2}$
So $E(X^{2})-\mu^{2}=\sigma^{2}\implies E(X^{2})-(E(X))^{2}=Var(X)=\sigma^{2}$ .
There are other ways to calculate the integral $\int_{-\infty}^{\infty}x^{2}e^{-x^{2}}\,dx$.
You can also use Gamma Function.