I recently stumbled upon an 'almost rational' integral, namely:
$$\int_0^{\pi/2} x \frac{\sqrt{\sin x}-\sqrt{\cos x}}{\sqrt{\cos x}+\sqrt{\sin x}} dx=0.231231222\dots \approx 0.231231231\dots= \frac{77}{333}$$
The error here is only:
$$\frac{77}{333}-I \approx 9 \cdot 10^{-9}$$
I don't think this integral has any known closed form (although I could be mistaken).
Do you know any integrals without a known closed form which are 'almost rational', meaning their value can be approximated by a rational number with the conditions:
$$|I-\frac{p}{q}|<10^{-7}$$
$$|p|,|q|<500$$
I hope there are some non-trivial integrals like the example I provided.
I tried to be as clear as possible, because the MathWorld page about almost integers is filled with 'questionable' entries.
One of the most remarkable integrals for me is the Borwein sequence. They do have closed form, but somehow I feel they should be mentioned here.
More interesting integrals.