One application of character theory in the investigation of structure of finite groups is for Burnside's theorem.
Can one mention some other results in Group theory, whose proofs are elementary from character theory, but difficult without character theory?
(There was a similar question on mathstack, but I did not find many answers in the direction above.)
If you do not wish to use character theory or calculations in a group ring for that matter, try this one: for a finite group $G$, let $g \in G$ be a commutator (that is, $g=[x,y]=x^{-1}y^{-1}xy$ for certain $x,y \in G$) and $n \in \mathbb{Z}$, such that gcd$(n, o(g))=1$ (here $o(g)$ denotes the order of $g$). Then $g^n$ is again a commutator.