$\newcommand{\unit}[1]{\hat{\mathbf{#1}}}$ Verify the truth of Stokes' theorem in the case when $\mathbf{v} = y\unit{i} + 2x\unit{j} + z\unit{k}$, if the path $C$ is a circle $x^2 + y^2 = 1$ in the $xy$ plane and the surface is the plane area bounded by $C$.
I am having trouble determine what the surface is. Is it cylinder cut by the plane formed by $\mathbf{v}$?

No. The surface in this case is the unit disk in the $xy$-plane (i.e. the part of the plane $z=0$ that satisfies $x^2+y^2\leq 1$).