Let's say I have a vector space $V$, and a linearly independent subset $L$ of $V$ along with a set $S$ that spans $V$ such that $$L \subseteq S.$$ Let $\Gamma = \{ K \subseteq V \ | \ L \subseteq K \text{ and } K \text{ is linearly independent}\}$ and put a partial order on $\Gamma$ by set-theoretic inclusion. I'm trying to conclude that $\Gamma$ contains a maximal element, i.e. that there is a maximal linearly independent subset of $V$ containing $L$.
My idea was this, choose any chain $L \subseteq K_1 \subseteq K_2 \dots$ of elements in $\Gamma$. If this chain doesn't have an upper bound, then at some point we'd have $V$ to be a proper subset of $K_i$ for some $i$ a contradiction, so every chain has an upper bound that being $V$.
Is this correct? I don't think so, the reason being that if $V$ has cardinality of $\mathbb{R}$ and $L$ is finite, then it could be possible that we have a chain $L \subseteq K_1 \subseteq K_2 \dots$ with $K_i$ adding $i$ points to $L$ and $K_i$ linearly independent, and then this chain never seems to have an upper bound and it can continue without us ever reaching the contradiction above.
What you have to prove is that there exists an element of $\Gamma$ that is an upper bound for the chain $K_i$.
Rather than an argument by contradiction, it is easier to do a direct construction of the upper bound: the union $\bigcup_i K_i$ is an element of $\Gamma$; and it is an upper bound for the chain. Both of these are relatively easy to verify.
Let me also add that by writing the chain in the form $K_1 \subseteq K_2 \subseteq\cdots$, you are fooling yourself a bit: you do indeed want to consider chains which are linearly ordered by inclusion; however, you do not want to restrict yourself to countable chains. The correct form of the chain is as a subset $\cal K \subset \Gamma$ such that the $\subseteq$ relation on $\Gamma$ restricts to a total order on $\cal K$: for all $K,K' \in \cal K$, either $K \subseteq K'$ or $K' \subseteq K$. Then the upper bound for the chain is simply $\bigcup_{K \in \cal K} K$ (and you still need to verify that this is an element of $\Gamma$).