Some of the applications of character theory are the proofs of Burnside $p^aq^b$ theorem, Frobenius theorem and factorization of the group determinant (the problem which led Frobenius to character theory).
I would like to know what are some of the other problems which has been solved by the application of character theory especially from number theory and group theory.
Character theory provides a better language to talk about certain group theoretic problems. Here is an example.
Goodness, that's a long definition. $\mathcal{M}$ is clearly a very difficult class of groups to study, impossible to understand. All the pieces fit together in some strange way, but it isn't quite clear what it all means.
Consider the following alternative definition.
The groups in both these definitions are called $\mathcal{M}$-groups, with proof of equivalence given yonder. We know a lot of things about them: $\mathcal{M}$-groups are solvable, supersolvable groups are $\mathcal{M}$-groups, normal subgroups of $\mathcal{M}$-groups and their quotients are both $\mathcal{M}$-groups, every solvable group can be embedded in an $\mathcal{M}$-group.
It is not at all obvious that these definitions are equivalent. The first definition was introduced $55$ years after the second, motivated by informal questions posed by several people who studied $\mathcal{M}$-groups using pairs. The purpose of this post is not to devalue the study of pairs in $\mathcal{M}$-groups, but to emphasize that character theory provides an easier language in which to study some problems in group theory, even when it is not logically necessary as in the case of Burnside's and Frobenius' theorems.