I recently started reading Arthur Engel's "Problem Solving Strategies" and it's first three chapters blew my mind. Most of the time in standard maths olymiads like IMO have a majority of questions based on Invariance, Coloring proofs and Extremal Principle.(First 3 chapters of book) and Functional Equations.
Is it enough to score good marks just by making a excellent grip on these 4 chapters??
If you are preparing yourself just to score good, then you are wasting your time. IMO preparation is meant for enhancing your thinking skills, problem solving skills and gaining knowledge.
Learn for yourself, not for marks.
Coming back to your answer, yes majority of question belong to the chapters that you listed. But as stated by @Hagen in his comment, there can be a question which test your thinking skills rather than knowledge and that single question can spoil your confidence and time.