Let us consider a function $f:[a,b]\rightarrow\mathbb{R}^n$. If $f\in L^\infty([a,b],\mathbb{R}^n)$, then $f$ is differentiable for all $x\in[a,b]$?
Can somebody give me good references where I can found smooth and differentiable properties of $L^\infty$ and $W^{1,\infty}$ spaces?
Not at all. The "functions" in $L^p$ spaces are defined as equivalence classes of functions (defined by changes on zero measure set). Those "functions" only have to be integrable, or in the case of $L^\infty$, (essentially) bounded. This means that you cannot even evaluate a typical $L^\infty$-function pointwise, and for sure most functions are not differentiable anywhere.
You can read about $L^\infty$ and Sobolev spaces in all standard books about functional analysis, I recommend also a look into Evans "Partial Differential Equations" e.g. for Sobolev's lemma that tells you that if a function is in a Sobolev space with high enough order, then it is also differentiable in the classical sense.