$e^{At}$ trivially satisfies both properties of semigroup namely
- $T(t+s) = T(t)T(s)$
- $T(0) = I$
Does there exist any other commonly used operators aside from $e^{At}$ that is a semigroup? Ignoring the obvious ones such as $M^{t}$ where $M \in \mathbb{R}$
The answer is yes. For examples, I suggest you the paper What is a semi-group?, by Einar Hille (page 55 of the book Studies in real and complex analysis edited by I. I. Hirschman, Jr.). In this paper, we read
After, the author consider other examples (involving fractional integration, harmonic functions, stochastic processes, diffusion equations and ergodic theory).