How can I prove this?
If in an A.P., Tm=n, Tn=m, prove d=-1.
Assume it is given that $m\ne n$.
You have $T(m)=n$ and $T(n)=m$. So,
$$a+(m-1)d=n\quad \text{and} \quad a+(n-1)d=m$$
Hint: Subtract the two equalities.
Notwithstanding the imprecision of the question, and assuming $m\neq n$:
The slope is $\frac{T_m-m}{T_n-n}=\frac{n-m}{m-n}=-1$
we have
$(T_i) $ arithmetic sequence
$$\implies T_n=T_m+(n-m)d $$
$$\implies m-n=(n-m)d $$
$$\implies (d+1)(n-m )=0$$
$$\implies d=-1$$
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Assume it is given that $m\ne n$.
You have $T(m)=n$ and $T(n)=m$. So,
$$a+(m-1)d=n\quad \text{and} \quad a+(n-1)d=m$$
Hint: Subtract the two equalities.