The relevant part of the integral definition of $Y_0$ is
$$-\frac{2}{\pi}\int_0^{\infty } e^ {-x \sinh t} \, dt$$
which should be asymptotic to
$$\frac{2}{\pi}\big( \ln\frac x 2 + \gamma \big)$$
Where $\gamma$ is the Euler-Mascheroni Constant. How can I evaluate that integral for small x?
It would be sufficient to find the logarithmic term, but I would also be interested in where the Euler-Mascheroni Constant comes from.
The intuition is that for small $x$ only the contribution for "large" $t$ is important. Thus, we expect that $\sinh t \sim \tfrac12 e^{t}$. So we approximate $$Y_0(x) \sim - \frac2{\pi} \int_0^\infty\!dt\,e^{-x e^{t}/2}= - \frac{2}{\pi}\int_{x/2}^\infty \!dz \frac{e^{-z}}{z}. \tag{1}$$
Indeed, we have that \begin{align*}\left|Y_0(x) +\frac2{\pi} \int_0^\infty\!dt\,e^{-x e^{t}/2}\right| & \leq \frac{2}{\pi} \int_0^\infty \!dt\,\left| e^{-x e^t/2} - e^{-x \sinh t} \right| \\ & = \frac{2}{\pi} \int_0^\infty \!dt\, e^{-x e^t/2} \underbrace{(1- e^{-x e^{-t}/2})}_{\leq x e^{-t}/2}=O(x) \end{align*} such that $(1)$ is correct (up and with the constant term).
Starting with $(1)$, we can proceed as follows: $$Y_0(x) \sim I=- \frac{2}{\pi}\int_{x/2}^\infty \!dz \frac{e^{-z}}{z}$$ We calculate $$\frac{dI}{dx} = \frac{e^{-x/2}}{\pi (x/2)} = \frac{1}{\pi(x/2)} + O(1)$$ and thus $$I = \frac{2}{\pi} \ln(x/2) + C $$ with $C$ a constant.
The constant is given by \begin{align*} C= \lim_{x\to0^+}\left[I - \frac{2}{\pi} \ln(x/2) \right]&=\frac{2}{\pi} \lim_{x\to0^+}\int_{x/2}^1 \frac{1-e^{-z}}z - \frac{2}\pi \int_1^\infty \frac{e^{-z}}z \\ & = \frac{2}{\pi} \int_{0}^1 \frac{1-e^{-z}}z - \frac{2}\pi \int_1^\infty \frac{e^{-z}}z .\end{align*} I am not sure there is an easy way to show that $C = 2 \gamma/\pi$.