Basic property of schemes?

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Let $X$ be a scheme. If $X$ happens to be affine then is it true that the canonical morphism

$$X\to\mathrm{Spec}\;\Gamma(X,\mathcal{O}_X)$$

is an isomorphism?.

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Yes. Moreover, this property characterizes affine schemes among all locally ringed spaces. See this MO comment for a proof sketch.