This is what I'm trying to do:

I'm unsure if determinants can actually be expanded in this way. If it were a 3x3, I would expand it into three 2x2 determinants with the terms of the first rows as constants in front of each one. Does the same principle apply here?
No, this doesn’t work. Two ways to see this:
The determinant has one term for each permutation of the indices. That implies that it’s $\pm1$ for every permutation matrix. Your expansion is zero for a permutation matrix that’s diagonal except $a_{23}=a_{32}=1$ and $a_{22}=a_{33}=0$.
Or: the determinant is the unique function from the set of matrices to the underlying field that is linear in each column, alternating in the columns (i.e. $0$ if two columns are identical), and yields $1$ for the identity. Your expansion doesn’t yield $0$ e.g. for a matrix with $1$s on the diagonal and $a_{23}=a_{32}=1$, even though the second and third columns are the same.