I have the following binary relation that is asymmetric: $$ \{\langle A,B\rangle , \langle B, C\rangle\} $$ I have the definition
A binary relation $R$ is reflexive on a set $S$ iff for all elements $d\in S$ the pair $\langle d, d\rangle$ is an element of $R$
Does this mean that the binary relation is reflexive on $S$?
Reflexivity holds for the empty set: Reflexivity means $\forall x, xRx$. If there is no $x$, then it is vacuously true. However, your relation $\{(A,B),(B,C)\}$ is not over the empty set, so I don't see how this applies.