Can we assign a truth value to a definition after we have define the term? For example, suppose I define $αβγ=\frac{df}{dx}$. Now if after I have define what $αβγ$ means state that $αβγ=\frac{df}{dx}$ isn't this a true a statement? But now the equality has become an equality about a statement and not for a definition?
Even in non-mathematical contexts we could define something. For example, "Man is a rational animal" is a definition. Again if after defining what "man" means if I state "Man is not a rational animal" isn't this a false statement?
So all definitions can be statements?
Indeed, after defining an object or notion by certain properties you can then make the true statement that the defined object or notion has these properties. The statement is then said to be "true by definition".
However, you asked "Can definitions become statements?", to which the answer is no: the definition stays a definition. A statement, even if it coincides almost exactly with some definition, is not that definition. You have to give the definitions of the involved notions and objects first to then make statements about them. So instead of the definition becoming a statement, you now have two things: a definition and a statement.