Let's say, $ \infty $ is not the biggest number, in fact, there is something bigger, somewhere. We want to try and count past $ \infty $, because it is not really an ordinal one, but a definition of something uncountable or too big to even count.
What numbers are bigger than $ \infty $?
$\infty$ can't be the biggest number, because it isn't a number. It's just a symbol used in limits. Ok, you can consider compactifications of real or complex numbers, but that's certainly not what you had in mind, because both are very far from "counting".