Could someone point me to a reference re canonical forms for classes of matrices in $M_n(\mathbb{C})$ which are unitarily similar?
That is, canonical representatives for the equivalence class defined by $A\sim B$ iff $\exists\, U$ unitary such that $A = UBU^*$.
Here's a reference:
I quote from the introduction:
For $2\times 2$ matrices, the canonical form is given by Theorem 2.4 in the paper: every matrix is unitarily similar to an upper triangular matrix with nonnegative entry in the upper right block, and to only one such (modulo permutation of the diagonal entries).
One can get rid of "modulo permutations" by introducing some order on $\mathbb C^2$, such as lexicographic order. This isn't particularly elegant, but this sort of thing is inherent in the problem. "What is a canonical form of vectors in $\mathbb C^n$ modulo permutation of coordinates?" is a special case of this question (diagonal matrices).
The canonical forms for larger matrices are much messier.