I stumbled upon this cute sum while messing about, and I want to see what other solutions people propose before I put forward my own (which may be unnecessarily complicated).
You can use any maths you like.
NB: $\displaystyle \mathrm{erf}(x)=\frac{2}{\sqrt{\pi}}\int_0^xe^{-t^2}dt$
Recall for all $x > 0$, $$\sinh x = \sum_{n=0}^\infty \frac{x^{2n+1}}{(2n+1)!} \quad\implies\quad \frac{\sinh \sqrt{x}}{\sqrt{x}} = \sum_{n=0}^\infty \frac{x^n}{(2n+1)!} $$ and the integral representation of $n!$ $$n! = \int_0^\infty x^n e^{-x}dx$$
The sum at hand can be rewritten as $$ \sum_{n=0}^\infty \int_0^\infty\frac{x^{n}}{(2n+1)!} e^{-x}dx = \int_0^\infty e^{-x}\left(\sum_{n=0}^\infty \frac{x^n}{(2n+1)!}\right)dx = \int_0^\infty e^{-x}\frac{\sinh\sqrt{x}}{\sqrt{x}}dx $$ Change variable to $t = \sqrt{x}$, this reduces to $$\int_0^\infty e^{-t^2}(e^t - e^{-t}) dt = e^{\frac14}\int_0^\infty \left(e^{-(t-\frac12)^2} - e^{-(t+\frac12)^2}\right)dt = e^{\frac14}\left(\int_{-\frac12}^\infty - \int_{\frac12}^\infty\right) e^{-t^2}dt\\ = e^{\frac14}\int_{-\frac12}^{\frac12} e^{-t^2}dt = 2e^{\frac14}\int_0^{\frac12} e^{-t^2}dt = e^{\frac14}\sqrt{\pi}\,\mathrm{erf}\left(\frac12\right) $$