This is exercise 5 of section 53 in Halmos' Measure theory.
Let $X$ be a locally compact Hausdorff space and $\mu^{*}$ an outer measure on the hereditary class of $\sigma$-bounded sets. Suppose $\mu^{*}(C)=\inf_{C \subset U, U \: \text{open}} \mu^{*}(U)<+\infty$ for every compact $C$.
Let $E$ be a $\sigma$-bounded set such that \begin{equation*} \mu^{*}(U)=\mu^{*}(U\cap E) + \mu^{*}(U\cap E^{c}) \end{equation*} for every open $U$. Is it true that $E$ is $\mu^{*}$-measurable ?
My guess is no, but I can't find a counter example.
$E$ is $\mu* measurable $
$\mu^{*}(U)=\mu^{*}(U\cap E) + \mu^{*}(U\cap E^{c})$ is also known as the Carathéodory's Criterion see here Any set $E$ satisfying this criterion is measurable. Remember $U$ is not even required to be measurable.