When considering non-abelian groups of order $p^2q$, where $p>q$ and $p,q>3$, two cases can be identified, when $q|p^2-1$.
Case 1: $q |p+1, q \nmid p-1$
Case 2: $q |p-1, q \nmid p+1$
Can someone guide me to prove that in Case 1, a unique semidirect product is present.
$p,q$ are distinct primes.
Thanks a lot in advance.
Let your group be $G$.
First of all, the Sylow $p$-subgroup $P$ will be a unique, as it has index $q < p$.
If $P$ is cyclic, then there is no (non-abelian) group $G$, as $q$ does not divide the order $p (p - 1)$ of the automorphism group of $P$.
Let then $P$ be elementary abelian, so that its automorphism group $A$ has order $$a = (p^{2} - 1) (p^{2} - p) = p (p - 1)^{2} (p + 1).$$
As $q > 2$, $q$ is the highest power of $q$ which divides $a$.
Let $Q$ be a Sylow $q$-subgroup. The groups $G$ are parameterised by the non-trivial homomorphisms $\phi : Q \to A$. The image of such a $\phi$ is thus a Sylow $q$-subgroup of $A$, and all these Sylow subgroups are conjugate.
This, and an easy additional argument with powers, show that all the groups arising from these $\phi$ are isomorphic.