Let $S$ be the boundary of a closed manifold $T$ embedded in $M$. I have to prove that the Poincaré dual of $S$ is $0$.
Assume $dim(M)=n,dim(T)=k$ with $k\le n$. Hence, $dim(S)=k-1$.
Let $[\eta_S]\in H_{DR}^{n-(k-1)}(M)$ be the (closed) Poincaré dual of $S$.
We have $i:S\to M$ embedding. We denote $\omega|_S:=i^*\omega$.
For every $\omega\in\Omega_c^{k-1}(M)$
$$ \int_S\omega|_S=\int_{\partial T}\omega|_S=\int_Td\omega|_S=0. $$
How can I conclude?
Here is a topological argument:
the inclusion $i:S\hookrightarrow M$ factors through $T$, hence by functoriality $i_*: H_*S \to H_*T \to H_*M$. The first map maps the fundamental class to zero. In particular the homology class which $S$ represents in $M$ is trivial.
Note that the boundary of a manifold is nullhomologous, by either stratifold theory, or the long exact sequence of the pair $H_k (T,\partial) \to H_{k-1}(\partial) \to H_{k-1} T$, where the first map maps fundamental class to fundamental class (which is then mapped to zero by exactness).