I want to show that if $X$ is a simplicial set we have a bijection $\text{colim}_{\Delta^{op}}X\cong \pi_0|X|$ with $|X|$ the geometric realization of $X$. So here $|X|=\coprod_{n\geq 0}X_n\times \Delta^n/\sim$ where $\Delta^n$ is the standard $n$-simplex and $\sim$ generated by $(x,\delta^{i}(t))\sim(d_i(x),t)$, $(x,\sigma^{i})\sim(s_i(x),t)$.
Here I have proved what if $X$ is a simplicial set, $\text{colim}_{\Delta^{op}}X\cong\text{coeq}(X_1\rightrightarrows X_0)$ and we have a way of seeing it as $X_0/ \sim $ where $x\sim x'$ if $\exists y\in X_1$ such that $d_0(y)=x,d_1(y)=x'$. So we can find just find a bijection between $X_0/\sim$ and $\pi_0(|X|)$.\
I thought about sending $[x]$ to $[(x,1)]$ with $(x,1)\in X_0\times \Delta^0$ but I'm not sure it works.
Do you have ideas ?
You seem to unfold the definitions correctly and be on track to a proof, so all good --- can you elaborate where/why you are struggling?
If you are categorically minded, you can also pursue a less 'computational' proof by observing that both sides of the purported isomorphism are left adjoint to the constant simplicial set functor.