If vector $v_{xy}$ is a vector on the $xy$ plane of magnitude $r$, and $v_{yz}$ is a vector on the $yz$ plane also of magnitude $r$, then $v_{xy} + v_{yx}$ results in vector $v$ of magnitude $R$.
How, given any vector $v$ to start with, can you calculate the two vectors $v_{xy}$ and $v_{yx}$ (which both have equal magnitude $r$) that add together to produce $v$ ?
A solution can be expressed in either cartesian or preferably polar coordinates.
(For clarity, I am not seeking to resolve into unit vectors, but specifically find the 2 vectors of equal magnitude from perpendicular planes that add to produce the vector $v$ of magnitude $R$)




Did you mean to say that $v_{xy} + v_{yz}$ results in a vector $v$ of magnitude $R$? And did you mean to say the vector $v$ is given? (You referred to $R$ as a magnitude, and then as a vector). If the vector $v$ is given, and hence its magnitude $R$ as well, then you can find the vectors $v_{xy}$ and $v_{yz}$ lying in the $xy$-plane and $yz$-plane respectively as follows:
Let $v_{xy} = \left[ \begin{matrix} v_{xy,1} \\ v_{xy,2} \\ 0 \end{matrix} \right] \text{ and } v_{yz} = \left[ \begin{matrix} 0 \\ v_{yz,2} \\ v_{yz,3} \end{matrix} \right]$ . Because these sum to the known vector $v = \left[ \begin{matrix} v_1 \\ v_2 \\ v_3\end{matrix} \right]$, we can immediately see that $v_{xy,1} = v_1$ and $v_{yz,3} = v_3$, so we now know those coordinates. What is left is to find the two coordinates $v_{xy,2}$ and $v_{yz,2}$.
To solve for these, we use the fact that $v_2 = v_{xy,2} + v_{yz,2}$, and because both $v_{xy}$ and $v_{yz}$ have the same magnitude (and hence the same squared magnitude), we can write $r^2 = v_{1}^2 + v_{xy,2}^2 = v_{yz,2}^2 + v_{3}^2$.
To solve this system of two equations, begin by substituting $v_{xy,2} = v_2 - v_{yz, 2}$ into the second equation, so we have \begin{align*} v_{1}^2 + (v_2 - v_{yz, 2})^2 & = v_{yz,2}^2 + v_{3}^2 \\ v_{1}^2 + v_2^2 - 2v_2 v_{yz, 2} + v_{yz, 2}^2 & = v_{yz,2}^2 + v_{3}^2 \\ v_{yz, 2} & = \frac{v_{3}^2 - v_{1}^2 - v_2^2}{- 2v_2} \\ v_{yz, 2} & = \frac{v_{1}^2 + v_2^2 - v_{3}^2}{2v_2} \\ \end{align*} and \begin{align*} v_{xy, 2} & = v_2 + \frac{v_{3}^2 - v_{1}^2 - v_2^2}{2v_2} \\ v_{xy, 2} & = \frac{v_2^2 + v_{3}^2 - v_{1}^2}{2v_2} . \end{align*}
So the two vectors are $ v_{xy} = \left[ \begin{matrix} v_1 \\ \frac{v_2^2 + v_{3}^2 - v_{1}^2}{2v_2} \\ 0 \end{matrix} \right] \text{ and } v_{yz} = \left[ \begin{matrix} 0 \\ \frac{v_{1}^2 + v_2^2 - v_{3}^2}{2v_2} \\ v_3 \end{matrix} \right]$.
Note: I've implicitly assumed that $v_2 \ne 0$. If $v_2 = 0$, then there are many such pairs of vectors, as the image in @David_G._Stork's answer shows.