One formulation of the Axiom of Choice is:
The Cartesian product of non-empty sets is always non-empty.
Cartesian product is defined as making "every possible pair" between elements of two sets. The implication is that through some aritrarily selected algorithm, we can select each element one-by-one, and pair it with another element (from another set). Does the Axiom of Choice imply that without assuming such an axiom, no such algorithm can exist? What if the elements are ordered? If I have a linearly ordered set, and I state that I my method of selection of elements is I will move from the lowest element to the highest element, am I still using the Axiom of Choice somehow? Is choosing even the lowest element in a set an exercise of the Axiom of Choice?
Thanks
Cartesian product of two sets is used to "make every possible pair". And that is true even without the axiom of choice. If you take the product of any two non-empty sets then the product of them is non-empty.
But what about Cartesian product of three sets? Are these pairs? Triplets? If these are pairs, what coordinate is the additional one, is it $((a,b),c)$ or $(a,(b,c))$? Well, these questions don't matter because we have a natural identification between all three options, triplets and the two type of pairs. So instead we can define redefine the Cartesian product of $A$ and $B$ as the set of functions from $\{0,1\}$ into $A\cup B$ such that $f(0)\in A$ and $f(1)\in B$. It is not hard to see why this gives us the same structure as ordered pairs.
The thing about this approach is that now the product of three sets can be thought of as functions from $\{0,1,2\}$ rather than pairs of pairs and so on. Whenever we add more sets, we just increase the index set.
Another wonderful benefit of this definition is its extendability to infinite products. If you insist that products are just pairs of pairs of pairs, and so on. What objects do you have when you take the product of infinitely many sets? It is a nice exercise to see that such object would have to be ill-founded. So we cannot have that in the presence of regularity (and we don't want to have that in general).
On the other hand, with the proposed definition as functions taking the product of infinitely many sets is easy. We have an index set $I$ and a family of sets $A_i$ and we just take functions such that $f(i)\in A_i$. Does that look familiar? It should. It is in fact the definition of a choice function.
So it turns out that the Cartesian product of sets is actually the set of choice functions from them. The axiom of choice assures that every family of non-empty sets has a choice function, and therefore the Cartesian product of any family of non-empty sets is non-empty. But as I said, for finite families of sets we can prove that we don't need the axiom of choice for choosing. That is, the Cartesian product of finitely many sets (however large they might be, just not empty) is non-empty. In particular $A\times B$ is never empty if neither set is empty.
You also made several other mistakes.
Without the axiom of choice it is not true that every set is ordered. Not well-ordered, and not linearly ordered. It is true that there are ordered sets, both well-ordered and linearly ordered, but it is possible for sets which cannot be linearly ordered to exist.
Not every linear order has a least element. And not every set which can be linearly ordered can necessarily be well-ordered.
Sets are not ordered sets. Ordered sets are sets which have a fixed structure endowed on them. If I just give you $\{a,b\}$, you can either order it as $a<b$ or $b<a$. But seeing how I haven't given you any information on what $a$ and $b$ are exactly, you have no preference for one way over the other. Therefore if you want this set to be ordered you have to choose an ordering.
It is possible that there is a countable family of pairs like that, that are so indiscernible from one another, that it is impossible to endow them all with orders at the same time. You can of course order each pair individually, and therefore you can order finitely many of them. But you cannot choose an order for each and every one of them at the same time without an appeal to the axiom of choice.
Regardless to that, if you are given structured sets. That is, sets which come along with a fixed structure, then it is possible to choose from each, under certain circumstances (e.g. the structures are well-orders, or there is some fixed element in each of the sets, etc.)
So if I would have given you $\{a,b\}$ and $a<b$; for each of the aforementioned pairs, then of course you can choose the minimal element in each pair.
But the point is that it is not necessary that every set can be ordered, and even if it is ordered, it is usually the case that there are many different (even if isomorphic) orders on each set, and to choose one for each set would be an appeal to the axiom of choice.