It looks to me like $$f(n):= \sum_{k=1}^{n}{(n\bmod k)}$$ is almost unique to $n$, with the only systematic exceptions being $(2^m-1, 2^m)$ pairs, which share a value for any $m \in \mathbb N$. In other words, the set $\{f(n): n\in\mathbb N\land n\neq 2^m \ \forall m\in\mathbb N\}$ shouldn't have many duplicate values.
As discussed in the answers, a handful of counterexamples have been found, but they seem more sparse than one would expect, and nobody has yet suggested why that might be, or what's special about the counterexamples found, apart from a moderate preponderance of small factors in the mean of the pair.
Although there's not much data to go on, it also looks like counterexamples may come in the form $(n,n+2i)$, or possibly even $(n,n+2^i)$, and I would be interested if anyone can find a case outside of those. The latter form would also include the $(2^m-1,2^m)$ exceptions, which seems elegant.
Also, if someone could set me straight on this: My understanding is that the term 'almost all' in this context means approaching $0$ density in the limit; so if one could show that the exceptions aren't necessarily finite, but they are less common than powers of two, would that be sufficient?
The approach above can be simplified to following general case.
Let $f(n):= \sum_{i=1}^{n}{(n\bmod i)}$ as described.
Given any pair of natural numbers $(n,k)$, we have $f(n)=f(n+k)$ if and only if
$$\sum_{i=1}^{k}{\sigma(n+i)}=2kn+k^2.$$
This seems to fit all known examples, including the $(2^m-1,2^m)$ pairs.