I am looking for effective algorithmic solutions for the following two problems:
Question 1: Is there a quick way to obtain for a given $n$ the list of all integer $n \times n$ matrices having only entries 0 and 1 that are invertible?
Question 2: Ditto, for given $n$ and $m$, matrices with largest entry $m$?
In the end I'm looking for a concrete implementation in GAP.
I do not think there is either function (nor indeed a non-brute force algorithm), though presumably asymptotically most matrices are invertible, so building matrices and testing invertibility would not be abysmal overkill.
Thus a very basic version (here for 0/1) is to take sets of possible rows (as combinations of different vectors) first (which saves on a factor of $n!$) before testing invertibility:
Then all matrices are obtained by permuting rows:
which will get all 12514320 matrices.