Constructing $n$-Cube, $n$-Cell and $n$-Orthoplex Groups

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What are the properties of the rotating cube, tetra- and octahedron that give them the group structures they have, and can those properties be generalised to get at the group structure of their higher-dimensional analogues? If so, is there a neat method that could be understood by an undergrad?

For background I'm preparing to start a course on groups next year, and this sort of thing is fascinating to me. Apologies if it's trivial!