I am aware that, given a group, there is no simple general procedure to construct the character table of the group (over complex numbers). However, for specific groups, we could use helpful additional information regarding the characters, (apart from orthogonality relations, etc.) to construct the character table. For instance, we know that the characters of a symmetric group are all integers.
Now suppose we have the group $S_5$, the symmetric group on 5 elements. Suppose we are given only the degrees of the irreducible representations/characters, namely $1,1,4,4,5,5,6$. Can this alone (apart from general results on characters) be used to derive the entire character table of $S_5$?
Depends on what you mean by "simple." There are algorithms which will spit out the character table of a finite group.
Just being given that it's $S_5$ is enough to derive the character table, so this question doesn't make sense.
However, let's say you're given the dimensions of the representations, but no other information about the group. That's not enough information to identify the group or reconstruct the character table in general. For instance, suppose I showed you that a group has four irreps, each one-dimensional. Well, now you know it's an abelian group of order four, but which one? They have different character tables.