I want to use the convergents of the continued fraction for $$c= \sum_{k=0}^\infty \frac 1{2^{2^k}} $$ - but of course a numeric software is very limited here, so I hope there exists a systematic expression for the entries of the continued fraction itself which I can use and evaluate directly.
So
Q: is there a functional description of the terms of the continued fraction for $c$
(I have a vague memory that I had once a copy of an article which dealt with systematic, but a-periodic continued fractions possibly related to constants like $c$ here, but I cannot remember more details, so a useful reference would help as well. At least I just found an old article of J. Shallit "Simple continued fractions for some irrational numbers" which discusses this but only for series with bases $3$ instead of $2$ in the denominators $c_3= \sum_{k=0}^\infty \frac 1{3^{2^k}} $ , and also I do not get the recipe to determine the entries of the continued fractions correctly)
Using Pari/GP with internal decimal precision of \p 200 I get the following:
c = sum(k=0,24,(2.0)^-(2^k))*1.0 \\ generate an approximation
%575 = 0.816421509022 \\ result: first digits of the constant
contfrac(c)
%574 = [0, 1, 4, 2, 4, 4, 6, 4, 2, 4, 6, 2, 4, 6, 4, 4, 2,
4, 6, 2, 4, 4, 6, 4, 2, 6, 4, 2, 4, 6, 4, 4, 2, 4,
6, 2, 4, 4, 6, 4, 2, 4, 6, 2, 4, 6, 4, 4, 2, 6, 4,
2, 4, 4, 6, 4, 2, 6, 4, 2, 4, 6, 4, 4, 2, 4, 6, 2,
4, 4, 6, 4, 2, 4, 6, 2, 4, 6, 4, 4, 2, 4, 6, 2, 4,
4, 6, 4, 2, 6, 4, 2, 4, 6, 4, 4, 2, 6, 4, 2, 4, 4,
6, 4, 2, 4, 6, 2, 4, 6, 4, 4, 2, 6, 4, 2, 4, 4, 6,
4, 2, 6, 4, 2, 4, 6, 4, 4, 2, 4, 6, 2, 4, 4, 6, 4,
2, 4, 6, 2, 4, 6, 4, 4, 2, 4, 6, 2, 4, 4, 6, 4, 2,
6, 4, 2, 4, 6, 4, 4, 2, 4, 6, 2, 4, 4, 6, 4, 2, 4]
Shallit's paper, which you've cited, gives a simple algorithm for generating these coefficients. It works for $\sum_{k=0}^{\infty}u^{-2^k}$ for integer $u\ge 3$; but he notes that it also works for $u=2$ (your case) with a slight modification.
Start with $$B_1=[1,3].$$ Then repeatedly apply the following rule: $B_{n+1}$ is generated from $B_n$ by appending the reverse of $B_n$ to $B_n$ and then adding $1$ and $-1$ to the two central terms. That is, $$ B_2=[1,4,2,1] \\ B_3=[1,4,2,2,0,2,4,1] \\ B_4=[1,4,2,2,0,2,4,2,0,4,2,0,2,2,4,1] \\ ... $$ This is correct as it stands, but generally one excludes zeroes from the entries of a continued fraction. To rectify that (this is the slight modification), generate $C_n$ from $B_n$ by contracting any subsequence $[a,0,b]$ down to $[a+b]$. That is, $$ C_2=[1,4,2,1] \\ C_3=[1,4,2,{\mathbf{4}},4,1] \\ C_4=[1,4,2,{\mathbf{4}},4,{\mathbf{6}},{\mathbf{4}},2,4,1]\\ ... $$ Now the elements of each $C_n$ (except the final $1$) are the entries in the continued fraction for $\sum_{k=0}^{\infty}2^{-2^{k}}$. (You'll note that they agree with the ones you've already found.) Just choose a large enough $n$ to get to the entry you need.