I'm trying to learn how to express a square root as continued fraction, but I can't get one thing.
The following example of $\sqrt{14}$ is from this page (click the image to see it at full size):
In the 2nd row of the table, can anyone please tell me where the 1 (in red) comes from? For instance, why can't it be 2, or 3, or 4?
This is my only doubt, which I've been trying hard to understand, but unable to.

Because $1$ is the greatest integer that is $\le \dfrac{\sqrt{14}+3}{5}$.
Remark: Recall the general continued fraction procedure. At any stage, we are looking at a number $x_n$, which is $\ge 1$ except possibly at the beginning. We compute $a_n=\lfloor x_n\rfloor$. If $a_n\ne x_n$, we define $x_{n+1}$ by $x_{n+1}=\dfrac{1}{x_n-a_n}$. Then $$x_n=a_n +\frac{1}{x_{n+1}}.$$ (There is a "better" algorithm for square roots of integers, and related numbers.)