If f is a real valued harmonic function in $C$ we know that $f_{xx} + f_{yy} = 0$. So, $f_{xx}$ and $f_{yy}$ exists, from this it is not correct to conclude that $f_x$ and $f_y$ are continuous right? Because there are differentiable function with discontinuous partial derivatives.
But if $f_x$ and $f_y$ were continuous we would have $f_{xy}=f_{yx}$. Does f is real valued help here in any way ?
So in short my doubt is, if f is a real valued harmonic function in $C$ can we tell $f_{xy} = f_{yx}$ ?
This is an excellent question. It is good to be skeptical: A function can have partial derivatives at a point while not being even continuous. See here for an example: A function whose partial derivatives exist at a point but is not continuous
But, $f_{xx}+f_{yy}=0$, with both $f_{xx}$ and $f_{yy}$ continuous, the usual definition for harmonicity, is a very strong condition. In fact, such functions are smooth, and so of course you get equality of mixed partials. There are many ways to prove this, depending on what you know.