From the definition of a derivative, we have that $$f'(a) = \lim\limits_{x\to a}\frac{f(x)-f(a)}{x-a}$$
or $$\lim\limits_{x\to a}f'(x) = \lim\limits_{x\to a}\frac{f(x)-f(a)}{x-a}$$
This leads me to believe we can write $$\lim\limits_{x\to a}(f(a)+(x-a)f'(x))=\lim\limits_{x\to a}f(x)$$
Which to me, implies that derivative allow us to obtain a good approximation for a function near $a$, and that this approximation will become increasingly accurate as $x\to a$.
However, couldn't we just as easily write
$$\lim\limits_{x\to a}(f(a)+2(x-a)f'(x))=\lim\limits_{x\to a}f(x)$$
since $$\lim\limits_{x\to a}(f(a)+(x-a)f'(x))=f(a)+\lim\limits_{x\to a}((x-a)f'(x))$$
and $$\lim\limits_{x\to a}((x-a)f'(a)) = 0 = \lim\limits_{x\to a}(2(x-a)f'(a))$$ provided that $\lim\limits_{x\to a}f'(a)$ exists.
Wouldn't this imply instead that $\lim\limits_{x\to a}(f(a)+2(x-a)f'(x))$ can be used to provide good approximations for the function near $a$? In fact, couldn't we replace $2$ with any other constant or function which has a limit at $a$?
Using such approximations, however, would obviously produce incorrect results in proofs such as those for the chain and product rules. So how can this contradiction be dealt with? Why is using $f'(x)$ simply more correct than using $2f'(x)$, even when the math doesn't necessarily seem to be demonstrating this?
Note that when $f$ is continuously differentiable at $a$, then $$\lim\limits_{x\to a}(f(a)+(x-a)f'(x))=\lim\limits_{x\to a}f(x)$$ is certainly true, but it is also true that
$$\lim\limits_{x\to a}(f(a)+g(x))=\lim\limits_{x\to a}f(x)$$
for any function $g$ such that $\lim_{x\to a}g(x)=0.$ Clearly, using the above limit equations as a basis for approximation is not going to get you anywhere meaningful.
Instead, without any limits, we can simply see from the definition of the derivative that when $f$ is differentiable at $a$, we can approximate the value of $f$ at $x$ as
$$f(x)\approx f(a)+(x-a)f'(a).\quad (1)$$
In fact, the expression in $(1)$ is the first order Taylor polynomial of $f$ around $a$. This may not be a "good" approximation; how "good" it is depends on your error tolerance, and there are known results on the bound of the error of such polynomials. See here.