Let $(X,\mathcal{H})$ be a measurable space. A measure on $(X,\mathcal{H})$ is a function $\mu : \mathcal{H} \rightarrow [0, \infty]$ such that
$\mu(\emptyset)=0.$
For any sequence of mutually disjoint sets $\{A_i\}_{i=1}^{\infty}$ in $\mathcal{H}$, then $\displaystyle \mu(\displaystyle\cup_{i=1}^{\infty}A_i)= \sum_{i=1}^{\infty}\mu(A_i) .$
Question 1: I would like to understand the true meaning of axiom two since the left hand side is independent of order and the right hand side depends on the order $A_1, A_2, \cdots$ or better still what is the correct way to define this.
Question 2: Is my definition of a measure correct?
Thanks.
It's actually just as typical to write $$\mu \left(\bigcup_{n \in \mathbb N} A_n \right)=\sum_{n \in \mathbb N} \mu (A_n).$$
The real meaning behind this is the notion of
summing over sets: Let $S$ be a set, and let $f:S \to [0,\infty]$ be a function, then we can formally define
$$\sum_{s \in S} := \sup\{f(s_1)+...+f(s_n) : n \in \mathbb N\}$$
(or alternatively, that $\{s_1,...,s_n\}$ is a countable subset of $s$, so we are taking a supremum over all partial sums.
This is known as countable additivity, but the index set is countable countable in the definition, to see why, perhaps see the definition of a $\sigma$-algebra.
Also note that this would be a poorly defined "sum" if we allowed negative terms, since conditionally convergent sums depend on the way we choose subsets. Here is a quick proof that it does not matter which notion you prefer:
Let $f$ be as before. It is clear that $$\sum_{n \in \mathbb N}f(n) \geq \sum_{n=1}^{N} f(n)$$
for all $N \in \mathbb N$, so we have that $$\sum_{n \in \mathbb N}f(n) \geq \sum_{n=1}^{\infty} f(n).$$
On the other hand, let $\{n_1,..,n_k\}$ be a finite set. Choose $N$ to be larger than any integer in this set. Then
$$f(n_1)+\dots f(n_k) \leq \sum_{n=1}^{N} f(n) \leq \sum_{n=1}^{\infty} f(n)$$
for all finite subsets, implying the reverse inequality.