$\mathbf{Y}=(Y_1, Y_2)^T$ is a bivariate Gaussian random vector with mean zero.
I want to prove that $Cov[Y_1^2, Y_2^2]=2\times(Cov[Y_1, Y_2])^2$.
I know that
$$Cov[Y_1^2, Y_2^2]=E[Y_1^2Y_2^2]-E[Y_1^2]E[Y_2^2]=E[Y_1^2Y_2^2]-Var[Y_1]Var[Y_2]$$
and
$$2(Cov[Y_1, Y_2])^2=2(E[Y_1Y_2]-E[Y_1]E[Y_2])^2=2(E[Y_1Y_2])^2$$ as $\mu_{Y_1}$,$\mu_{Y_2}$ are 0.
What is the next step I should proceed?
Some facts:
Using these facts, we can write,
$$\begin{eqnarray} \mathbb{E}[Y_1^2Y_2^2] &=& \mathbb{E}[\mathbb{E}[Y_1^2Y_2^2 | Y_2]]\\ &=& \mathbb{E}[Y_2^2\mathbb{E}[Y_1^2|Y_2]]\\ &=& (1-\rho^2)\sigma_1^2\mathbb{E}[Y_2^2] + \frac{\rho^2\sigma_1^2}{\sigma_2^2}\mathbb{E}[Y_2^4]\\ &=& (1-\rho^2)\sigma_1^2\sigma_2^2 + 3\rho^2\sigma_1^2\sigma_2^2 \end{eqnarray}$$
Substitute this into your expression for $Cov(Y_1^2,Y_2^2)$ to get $2\rho^2\sigma_1^2\sigma_2^2$ which is identically $2(Cov(Y_1,Y_2))^2$.