I don't understand the book's explanation.
1) So, c = a times b times sin angle. Is this the formula for solving that kind of problem? Yet the last problem I did about this had cos instead of sin -

what's the difference?
2) How is it determined that $90$ is the angle? It fails to explain that.
3) Where does the line $"250 - 90 = 160"$ come from? All I see in the problem are $250$, $18$, and $12$. There's no $90$. Where is the book getting $90$ from?
4) How is it determined that the $160$ degrees is in "positive x axis"? What indicates that?

1) The first image you posted discusses the cross product, the second the scalar (aka "dot") product. This explains the cosine/sine confusion.
2) The problem specifies that $\vec{a}$ is in the $xy$-plane and $\vec{b}$ is parallel to the $z$-axis, so they must be perpendicular (i.e. make a 90-degree angle).
3) The formula they're using is $$\text{angle from $x$-axis to $\vec{a}$} = \text{angle from $x$-axis to $\vec{c}$} + \text{angle from $\vec{c}$ to $\vec{a}$} .$$ We're guaranteed that the cross-product $\vec{c} = \vec{a} \times \vec{b}$ is perpendicular to both $\vec{a}$ and $\vec{b}$, so $\text{angle from $\vec{c}$ to $\vec{a}$} = 90^\circ$ (well, it would be $-90^\circ$ instead if $\vec{b}$ pointed along $-\vec{z}$ instead of $+\vec{z}$; this is why drawing diagrams is helpful).
4) Angles in the $xy$-plane are measured from the positive $x$-axis by convention. There's nothing more to it.