This is a past paper exam question, I don't really understand how to define this quotient structure.
The relation is on $\Bbb{N}$
In the preceding question I proved that this relation is an equivalence.
The equivalence class of some (a,b), which I will denote $[(a,b)]_\sim$ = {(c,d) | a+d=b+c}
I then worked through a few example classes to determine the pattern and see if I could describe the quotient set:
$[(a,a)]_\sim = \{(c,c) | c \in \Bbb{N}\} $
$[(1,2)]_\sim = \{(c,d) | c \in \Bbb{N} , 1+d = 2+c\} = \{(c,c+1) | c \in \Bbb{N}\}$
$[(1,3)]_\sim = \{(c,d) | c \in \Bbb{N} , 1+d = 3+c\} = \{(c,c+2) | c \in \Bbb{N}\}$
$[(2,1)]_\sim = \{(c,d) | c \in \Bbb{N} , 2+d = 1+c\} = \{(c,c-1) | c \in \Bbb{N}\}$
Clearly, $\forall (a,b) \in \Bbb{N} \times \Bbb{N}, [(a,b)]_\sim = \{(c,c+b-a) | c \in \Bbb{N}\}$
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I feel like I've understood the relation, but the question asks me "By considering representative members of these classes, or otherwise, describe how operations of $+$ and $\times$ may be defined to form a quotient structure.", and I don't really understand that. Clearly, the quotient set is the set of all possible values of b-a, which is countably infinite. I don't understand how to define that using operations of + and X though.
It doesn't seem that there's really any motivation to define addition or multiplication in the quotient structure a certain way (at least, not from what you've posted), so here's a big motivation: $\Bbb N/\sim$ is quite often how the set of integers is defined using $\Bbb N$. The idea is that $(a,b)$ represents $a-b$ (which needn't make any sense if we're dealing only with natural numbers), and that $(a,b)\sim(c,d)$ iff $a-b=c-d$. In the context of integers, this is of course equivalent to $a+d=b+c$, but since we're dealing with natural numbers only, we need to use the "$a+d=b+c$" version.
I will (temporarily) call the addition and multiplication operations on $\Bbb N/\sim$ by $\oplus$ and $\odot$, to distinguish from the operations $+$ and $\cdot$ on $\Bbb N$. The operation $-$ will represent subtraction on the integers as we're used to (that is, as a superset of $\Bbb N$, rather than being derived as a quotient of $\Bbb N$), just to give us an idea of what we need to happen with $\oplus$ and $\odot$. Now, $$(a-b)+(c-d)=(a+c)-(b+d),$$ so we'll need $$[(a,b)]_\sim\oplus[(c,d)]_\sim:=[(a+c,b+d)]_\sim.$$ Also, $$(a-b)\cdot(c-d)=a\cdot c-a\cdot d-b\cdot c+b\cdot d=(a\cdot c+b\cdot d)-(a\cdot d+b\cdot c),$$ so we'll need $$[(a,b)]_\sim\odot[(c,d)]_\sim:=[(a\cdot c+b\cdot d,a\cdot d+b\cdot c)]_\sim.$$
You should be able to show that each $\sim$-equivalence class has a unique representative $(a,b)$ such that $a=1$ or $b=1$ (or $a=b=1$). This should help you to prove that $\oplus$ and $\odot$ are in fact well-defined.
Once we're done with that, we can call $\Bbb N/\sim$ by "$\Bbb Z$", noting that $[(1,1)]_\sim$ is the $\oplus$-identity element of $\Bbb Z$ and that $[(2,1)]_\sim$ is the $\odot$-identity element. Also, for any $[(a,b)]_\sim\in\Bbb Z$, the $\oplus$-inverse of $[(a,b)]_\sim$ is $[(b,a)]_\sim$. Now, we have a natural inclusion $\Bbb N\to\Bbb Z$ given by $n\mapsto[(n+1,1)]_\sim$, and you can see that this inclusion maps $n+m$ to $[(n+1,1)]_\sim\oplus[(m+1,1)]_\sim$ and maps $n\cdot m$ to $[(n+1,1)]_\sim\odot[(m+1,1)]_\sim.$
This inclusion's operational compatibility allows us to simply call $[(n+1,1)]_\sim$ by "$n$" and $[(1,n+1)]_\sim$ by "$-n$" for all (positive) $n\in\Bbb N$, and we call $[(1,1)]_\sim$ by "$0$"; likewise, call $\oplus$ by "$+$" and $\odot$ by "$\cdot$." In this way, we effectively treat $\Bbb N$ as a substructure of this new structure $\Bbb Z$ that we've constructed (and which has all the properties we're used to), while at the same time simplifying the notation we were using in $\Bbb Z$ before.