For real matrices $A$ it holds that $$\det\,\big(e^A\big)=e^{\mathrm{tr}\,A}$$ so we can write $$\mathrm{tr}=(\exp)^{-1}\circ \;\det\;\circ\;(\exp).$$ Is this interpretation of trace as the "conjugate" of the determinant under the exponential map used anywhere, or useful for anything? It seems neat but I have not come across it before.
Edit: note that the $(\exp)$ on the left (of which an inverse is taken) is the natural logarithm $\ln$ for real numbers, not for matrices (I think!) because it is applied after finding the determinant.
It is absolutely useful in the study of Lie groups, where the exponential map takes us from a Lie algebra to the corresponding Lie group, which allows for the study of these groups "at the algebra level".
I'm not sure if your particular property ends up being useful, but one certainly uses the fact that eigenvalues are mapped as $\lambda \mapsto e^{\lambda}$.