Let $\sigma_1(x,y,z) = x + y + z$, $\sigma_2(x,y,z) = xy + xz + yz$ and $\sigma_3(x,y,z) = xyz$.
When is the map $\Phi: \mathbb{R}^3 \to \mathbb{R}^3, \Phi\,(x,y,z) = \begin{pmatrix} \sigma_1(x,y,z) \\ \sigma_2(x,y,z) \\ \sigma_3(x,y,z)\end{pmatrix}$ a local $C^{\infty}$-diffeomorphism?
We have that $\Phi \in C^{\infty}$. Now:
$$\det [D \Phi(x,y,z)] = x^2(y - z) + y^2(z - x) + z^2(x - y) = (x - z)(y - z)(x - y)$$
So let $\Omega$ be the union of the three planes: $(x = y)$, $(x = z)$, $(y = z)$. We have that $\Phi$ is a local $C^{\infty}$-diffeomorphism near each $(x,y,z) \in \Bbb R^3 \setminus \Omega$