Consider $V$ as a subspace in $\mathbb{R}^4$ where $V= \text{span}\{(2,1,0,1),(2,-1,-1,-1),(3,0,2,3)\}$. Find a subspace $W$ so that $\mathbb{R}^4=W\oplus V$.
If I find a vector in $W$ that is linearly independent of those in $V$ and it spans $W$, is that enough for what i have to find?
That is almost enough; you just also have to prove that the generators of $V$, $(2,1,0,1)$, $(2,-1,-1,-1)$, $(3,0,2,3)$, are linearly independent.
In short, you need find a vector $v$ and show that $(2,1,0,1), (2,-1,-1,-1), (3,0,2,3),$ and $v$ are all linearly independent. Then let $W = \text{span}(v)$. This will imply (i) that $W \cap V = \{\textbf{0}\}$, and (ii) that $W + V = \mathbb{R}^4$.