
Why is this $\mathbf{w}-\mathbf{v}$ and not $\mathbf{v}+\mathbf{w}$? I understand $\mathbf{v}+\mathbf{w}$ means $\mathbf{w}$ vector is placed at end of $\mathbf{v}$. However book didn't explain well how $\mathbf{w}-\mathbf{v}$ works here. I can think of it as $c^2 - a^2 = b^2$ which is essentially same thing as $\mathbf{w}-\mathbf{v}$. I can't however see how the vector property works here for $\mathbf{w}-\mathbf{v}$ or $\mathbf{w}+(-\mathbf{v})$.
$w-v = w+(-v)$
Note that $-v$ is $v$ with the head and tail of the arrow swapped. Then, you can add them using the tail to head method to get the vector $w-v$.