Does the number pi have any significance besides being the ratio of a circle's diameter to its circumference?

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Pi appears a LOT in trigonometry, but only because of its 'circle-significance'. Does pi ever matter in things not concerned with circles? Is its only claim to fame the fact that its irrational and an important ratio?

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It is difficult to know if a circle is not lurking somewhere, whenever there is $\pi$, but the values of the Riemann zeta function at the positive even integers have a lot to do with powers of $\pi$: see here for the values.

For instance, you can prove that the probability that two "randomly chosen" positive integers are coprime is $\frac{1}{\zeta(2)} = \frac{6}{\pi^2}$.

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$\pi$ appears in Stirling's approximation, which is not obviously related to circles. This means that $\pi$ appears in asymptotics related to binomial coefficients, such as

$$\displaystyle {2n \choose n} \approx \frac{4^n}{\sqrt{\pi n}}.$$

In other words, the probability of flipping exactly $n$ heads and $n$ tails after flipping a coin $2n$ times is about $\frac{1}{\sqrt{\pi n}}$. This asymptotic also suggests that on average you should flip between $n + \sqrt{\pi n}$ and $n - \sqrt{\pi n}$ heads.

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Because of the formula $e^{i\pi}+1=0$ you will find $\pi$ appearing in lots of places where it's not clear there is a circle, e.g in the normal distribution formulae.

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Yes, the ratio $\pi$ of a circle's circumference to its diameter shows up in many, many places where one might not expect it!

One partial explanation (similar in spirit to "circles lurk everywhere") is that the equation for a circle is a $quadratic$ (eg. $x^2+y^2 = r^2$.) After nice linear functions, the next most commonly used functions are quadratic functions and everywhere one runs into a quadratic function, a trig substitution (e.g. $x = r \cos \theta; y=r\sin \theta$) may be useful, turning the quadratic function into something involving $\pi.$ This explains the antiderivative $\int \frac{1}{1+x^2} dx$ involving $\pi$, the sum of reciprocals of squares $\sum^\infty\frac{1}{k^2}$ involving $\pi$ and the area under the Gaussian distribution involving $\pi$. And so on....