This is from Humphrey's Lie algebra text, page 17:
So Humphrey defines what is semisimple here:

Now the next page explains why the Jordan decomposition is useful and he proves a useful result:

Now the part that I am confused about is why are we allowed to choose a basis such that our matrix is diagonal? Because x being semisimple implies diagonalizability if our field is algebraically closed but I don't think we ever made that assumption here so why is this possible?
The first paragraph of Chapter II says:
The section from which you clipped the second screenshot does relax the assumption that $\operatorname{char} \mathsf{F} = 0$, but as far as I can tell it is still assumed to be algebraically closed. In fact, given what precedes the assumption (after “Moreover...”), it seems that this is the main reason for making such an assumption.