On page 8 of "A gentle introduction to the Finite Element Method" by Francisco–Javier Sayas, a space is defined on a domain omega with an overbar.
Previously he had used the omega domain to represent the physical domain. Does anyone have any ideas as to what the overbar means?
The overbar usually means 'closure', in some appropriate contextual sense. It's $\Omega \cup \{\text{something else}\}$ so that extra properties are satisfied. Very likely in this case it's for completentess, i.e. so that Cauchy sequences in $\overline{\Omega}$ converge in $\overline{\Omega}$ (though don't take my word for it).