Let $\mathfrak{g}$ be a seimisimple Lie algebra over $\mathbb{C}$, $\mathfrak{h}$ a Cartan subalgebra, $\mathrm{Aut}^0(\mathfrak{g})$ the connected component of the identity in the automorphisms group of $\mathfrak{g}$. What I want to prove is there exists an isomorphism $$\left \{\phi \in \mathrm{Aut}^0(\mathfrak{g}) \mid \phi(\mathfrak{h})=\mathfrak{h} \right \}/\left \{\phi \in \mathrm{Aut}^0(\mathfrak{g}) \mid \phi_{\mid \mathfrak{h}} = \mathrm{id}_{\mathfrak{h}} \right \} \cong \mathrm{Weyl \ group}.$$ Denote $N$ by $\left \{\phi \in \mathrm{Aut}^0(\mathfrak{g}) \mid \phi(\mathfrak{h})=\mathfrak{h} \right \}$. It is obvious that every element in $\mathrm{Aut}(\mathfrak{g})$ preserves the Killing form of $\mathfrak{g}$, in particular, every element in $N$ as well and for every element $\phi$ in $N$, we have $\phi(\alpha^*) = (\alpha \circ \phi^{-1})^{*}$ where $\alpha^*$ is the dual of an eigenform, i.e. $\alpha(H) = B(H,\alpha^*)$ ($B$: the Killing form). On the real vector space $E = \sum \mathbb{R}\alpha^*$ we have $$B(\phi X,Y) = B(X,\phi^{-1}Y),$$ therefore with respect to the Killing form as a quadratic form, elements in $N$ take value in $O(E)$ - the orthogonal group, i.e. there exists a canonical map $$\begin{align*} \psi: N & \to O(E) \\ \phi & \mapsto \left \{\phi: \alpha^* \mapsto \phi(\alpha^*) \right \} \end{align*},$$ and this map is factored through $N/\left \{\phi \in \mathrm{Aut}^0(\mathfrak{g}) \mid \phi_{\mid \mathfrak{h}}=\mathrm{id}_{\mathfrak{h}} \right\}$ since $\left \{\phi \in \mathrm{Aut}^0(\mathfrak{g}) \mid \phi_{\mid \mathfrak{h}}=\mathrm{id}_{\mathfrak{h}} \right\}$ is precisely the kernal of $\psi$; in particular, the induced map is injective. If we can prove that this map takes value in the Weyl group then we deduce an isomorphism. Indeed, this map is surjective for each reflection $S_{\alpha}$ because in $\mathfrak{g}$, the subalgebra $g_{\alpha} \oplus g_{-\alpha} \oplus [g_{\alpha},g_{-\alpha}]$ is isomorphic to $\mathfrak{sl}_2$ and we can choose element $X,H,Y$ in this subalgebra such that they correspond to standard basis of $\mathfrak{sl}_2$, a direct computation shows that $\psi(e^{\mathrm{ad}(X)}e^{\mathrm{ad}(-Y)}e^{\mathrm{ad}(X)}) = S_{\alpha}$. What is left here is the fact that the induced map of $\psi$ takes values in the Weyl group.
From the semisimplicity, $\mathrm{Aut}^0(\mathfrak{g})$ is the inner automorphism group $\left \langle e^{\mathrm{ad}(x)}\mid x \in \mathfrak{g} \right \rangle$ but I do not know how to proceed.
Since the Bourbaki style is terrible to track down all the detals, I post this one to help others those who want to read a full proof of this problem; of course, I adapt modern notations.
Fix a base $\Delta$ for the root system $\Sigma$. Denote $$\Sigma^* = \left \{\alpha^* \mid \alpha \ \text{is a root} \ \right \}$$ $$\mathrm{Aut}(\Sigma^*,\Delta) = \left \{ \ \text{elements in} \ \mathrm{Aut}(\Sigma^*) \ \text{stabilize} \ \Delta \right \}.$$ We are now at the position to prove that if $\phi \in N$ s.t. $\psi(\phi)$ induces an element in $\mathrm{Aut}(\Sigma^*,\Delta)$ then $\delta=\psi(\phi)$ is induced by an element in $Z = \left \{\phi \in \mathrm{Aut}_0(\mathfrak{g}) \mid \phi_{\mid \mathfrak{h}} = \mathrm{id}_{\mid \mathfrak{h}} \right \}$. The subgroup generated by $\delta$ has a finite number of orbits on $\Sigma^*$, let $U$ be such an orbit of cardinal $r$, denote $$g_U = \bigoplus_{\alpha^* \in U} g_{\alpha}.$$ Let $\alpha_1^*\in U$ and I define $\alpha_i^* = \delta^{i-1}(\alpha_1^*) = (\alpha_1 \circ \delta^{1-i})^* \ \forall \ i = \overline{1,r}$. Thus $U = \left \{\alpha_1^*,...,\alpha_r^* \right \}$. Let $X_1$ b a non-zero element in $g_{\alpha_1}$. We are going to prove that there exists a non-zero scalar $c_U$ such that $\delta^r(X_1)=c_U X_1$. To do this, recall that $U$ is an orbit, therefore $\delta^r(\alpha_1^*) = \alpha_1^*$, equivalently, $(\alpha_1 \circ \delta^{-r})^* = \alpha_1^*$. We claim that $\delta^r(X_1) \in g_{\alpha_1}$. Indeed, for all $H \in \mathfrak{h}$, $$\begin{align*} [H,\delta^r(X_1)] & = \delta^r[\delta^{-r}(H),X_1] \\ & = \delta^r\left((\alpha_1\circ \delta^{-r})(H)X_1 \right) \\& = (\alpha_1\circ\delta^{-r})(H) \delta^r(X_1) \\ & = B(H,(\alpha_1 \circ \delta^{-r})^*) \delta^r(X_1) \\ & = B(H,\alpha_1^*)\delta^r(X_1) \\ & = \alpha_1(H)\delta^r(X_1). \end{align*}$$ But by the semisimplicity of $\mathfrak{g}$, $\mathrm{dim}(g_{\alpha})=1$, hence $\delta^r(X_1)$ and $X_1$ are proportional, prove our claim. By the definition of other $X_i$, we deduce that $$\delta^r_{\mid g_U} = c_U.\mathrm{id}_{g_U}.$$ We shall twist $\delta$ by an element of $Z$ so that the resulting automorphism still comes from an element in $Z$. For each functional, $$\Theta: \bigoplus_{\alpha \in \Sigma} \mathbb{Z}\alpha^* \to \mathbb{C}^*$$ We define an element $Z$, denoted by $f(\Theta)$, by the following rule $$\begin{cases} f(\Theta)_{\mid g_{\alpha}} = \Theta(\alpha^*)\mathrm{id}_{\alpha} \\ f(\Theta)_{\mid \mathfrak{h}} = \mathrm{id}_{\mathfrak{h}} \end{cases}$$ It is clear that $f(\Theta) \in Z$. Moreover, $$(\delta \circ f(\Theta))(X_1) = \delta(\Theta(\alpha_1^*)X_1) = \Theta(\alpha_1^*)\delta(X_1) = \Theta(\alpha_1^*)X_2.$$ Iterating this process by successively applying $\delta \circ f(\Theta)$, we deduce that $$(\delta \circ f(\Theta))^r(X_1) = c_U\prod_{i=1}^r \Theta(\alpha_i^*)X_1 = c_U \Theta \left(\sum_{i=1}^r \alpha_i^* \right)X_1.$$ Again, this implies that $$(\delta \circ f(\Theta))^r_{\mid g_U} = c_U \Theta \left(\sum_{i=1}^r \alpha_i^* \right) \mathrm{id}_{g_U}.$$ Let write our fixed base $\Delta$ as $\Delta = \left \{\beta_1^*,...,\beta_n^* \right \}$. Since this is a base, there exists $a_1^U,...,a_1^U \in \mathbb{Z}$, have same sign, not all zero such that $\alpha_1^*= \sum_{i=1}^n a_i^U \beta_i^*$, successively apply $\delta$ and recall that $\delta \in \mathrm{Aut}(\Sigma^*,\Delta)$ we deduce the existence of $m_1^U,...,m_n^U \in \mathbb{Z}$ of same sign, not all zero such that $$\sum_{i=1}^r \alpha_i^* = \sum_{i=1}^n m_i^U \beta_i^*.$$ Thus, define $c'_U = c_U\Theta \left(\sum_{i=1}^r \alpha_i^* \right) = c_U \prod_{i=1}^n \Theta(\beta_i^*)^{m_i^U}$, we can choose $\Theta$ such that for all orbits $U$, $c_U' \neq 1$. This is possible, because it is equivalent to choose $\Theta(\beta_i^*) = t_i$ are elements in $\mathbb{C}^*$ such that all polynomial $c_U\prod_{i=1}^n t_i^{m_i^U} - c'_U$ vanish. So far, what we've done is to show that it is possible to choose $\Theta$ such that $\delta \circ f(\Theta)$ does not have $1$ as an eigenvalue on the subspace $\oplus_{\alpha \in \Sigma} g_{\alpha}$.
Now since $\mathrm{Aut}^0(\mathfrak{g})$ is a connected Lie group, every element can be written as product of some $e^{y}$ with $y \in \mathrm{Lie}(\mathrm{Aut}^0(\mathfrak{g})) \subset \mathrm{Der}(\mathfrak{g}) \overset{\text{semisimplicity}}{=} \mathrm{ad}(\mathfrak{g})$; thus, each element in $\mathrm{Aut}^0(\mathfrak{g})$ is a product of elements of form $e^{\mathrm{ad}(x)}$ with $x \in \mathfrak{g}$. We are at the position to prove that the generalized $0$-space of $\delta \circ f(\Theta) - \mathrm{id}$ has dimension at least the dimension of $\mathfrak{h}$, which equals $\mathrm{rank}(\mathfrak{g})$. To illustrate how to do this, we consider the case $\delta \circ f(\Theta) = e^{\mathrm{ad}(x)}$ only. Since we are working over $\mathrm{C}$, $\mathrm{ad}(x)$ is similar to a Jordan matrix $J$, read $\mathrm{ad}(x) = AJA^{-1}$ for some $A \in \mathrm{GL}(\mathfrak{g})$. Thus, $\mathrm{dim} \mathfrak{g}^0(\mathrm{ad}(x))$ is precisely the number of $0$ on the diagonal. Moreover, $e^{\mathrm{ad}(x)} - \mathrm{id} = A(e^J - 1)A^{-1}$ and $e^{\lambda}=1 \Leftrightarrow \lambda=0$, we conclude that the number of $0$ on the diagonal of $e^J - \mathrm{id}$ equals of $\mathrm{ad}(x)$. Finally $$\mathrm{dim} \bigcup_{k \geq 1} (\delta \circ f(\Theta) - \mathrm{id})^k = \mathrm{dim} \mathfrak{g}^0(\mathrm{ad}(x)) \geq \mathrm{rank}(\mathfrak{g}) = \mathrm{dim}\mathfrak{h}.$$ By the assumption of no eigenvalue $1$ on the complement $\oplus_{\alpha \in \Sigma}g_{\alpha}$, we see that $\delta \circ f(\Theta) - \mathrm{id}$ is nilpotent on $\mathfrak{h}$. On the other hand, $\delta \circ f(\Theta)$ permutes a base so it has finite order (it is an element of a finite symmetric group). Consequently, its characteristic polynomial (and hence minial polynomial) divides $x^k-1$ for some $k$, the latter polynomial has all roots as simple roots so the Jordan blocks of $\delta \circ f(\Theta)$ are all of size $(1 \times 1)$; i.e. $\delta \circ f(\Theta)$ is diagonalizable. Combine this with the previous assertion of $\delta \circ f(\Theta)$ being nilpotent, we deduce that $\delta \circ f(\Theta)_{\mid \mathfrak{h}} = \mathrm{id}_{\mathfrak{h}}$, as desired.